Possible Head gasket issue??
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If the system over-pressurizes again and you can get your hands on a CO/combustion test kit, check it with that. In your case I would set up the tester and check the coolant in the overflow bottle as you slowly release some of the pressure/gases into the overflow from the radiator by very slowly loosening the radiator cap. Be damn careful. And it only takes a little turning of the cap to allow the gases out and into the overflow. The test kits are relatively cheap, easy to get and very accurate. Good luck!






