Quick whiff of coolant
Sounds like the leak is too small to leave any staining at this point. I'd keep an eye on the coolant level. Small leaks at the water pump don't always leave staining or cause any dripping when the engine is not running (e.g. no puddles in the garage, etc.) so, while it might not yet be identifiable, I wouldn't rule out the water pump at this point. But, as mentioned above, it could be coming from a variety of potential sources.
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...and immediately replace the reservoir cap to rule that in/out as a source out...they are a "wear" item
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I'd still keep an eye on coolant level though, especially if a new cap doesn't fix it. To catch a whiff of this (even without a visible leak present or enough loss to require adding some fluid) could suggest that it's a very tiny amount quickly burning off on a hot surface, leaving no trace but an odor.
The leak is so small at this point that it burns off immediately, leaving no visible trace, only the odor.
I too would not use additives in your coolant from personal experience. You could not only stop a leak, but also stop proper coolant flow - thus overheating.
If you think it might be the heater core, and you want to rule it out, you could by pass it with an 8 dollar U-hose and 10 minutes of work to put it on.













