LT1 hard to start
The other problem that I have encountered that matches your symptom is the hi res signal being gone on the opti and if I gave it gas or pumped it while starting it would eventually start. It would run too but you could tell it was a little sluggish and just generally "pissy". That points back to a bad opti or the harness that plugs into it. There are known for going bad too. Typically they set a trouble code if the hi or low res goes out but if it hasn't ran long enough that way it may not have set the code yet.
You can try spraying the harness that plugs into the opti down with some electrical cleaner. It will clean and absorb moisture in the wires. It's worth a shot. Otherwise, I say the opti is the issue, again.

EDIT: Ok I missed the part about it running great after started. Sorry. Is that your opinion of running great or are you familiar with an LT1 cars performance? I'm still leaning towards it being the hi res signal is not showing for the opti. It can run "ok" with the low res but starting will always be an issue.
I thought fuel pressure when cranking and at idle was supposed to be a minum of 48? I could be wrong though. Try cycling the key 4 times before you acually start cranking it over. If it starts right up I would say it's fuel related. If pressue is back to zero within 5 minutes I would say you are losing fuel pressue somewhere for sure and you're on the right track. However, if it doesn't fire right off after cycling the key, then I say go back to troubleshooting the opti.
Last edited by kyoytey1693; Jul 24, 2012 at 11:30 PM.
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