Thats weird, I had a 1994 LT1, it had a 180 degree thermostat with the fans reprogrammed for that same setting and it never went over 180, on the highway it would go and stay little bit under 180. You got to bleed both screws, theres one by the throttle body, passenger side, and the other is on the thermostat housing. Make sure both fans turn on with the a/c on, theres a setting that turns your fans off on the highway, that setting is determined by speed and temperature, in other words, if you have a bad/burnt fan motor, you will not notice it on the highway since the car gets enough air to cool engine as its running. When you're at a stop, driver side fan should be on, and when you turn the a/c, secondary fan should also turn on. If they don't turn on, you may have a faulty relay, or a bad/burnt motor. I had a secondary fan fail on me, and it caused a very similar situation to yours. When it overheats, does it do it having the a/c on? have you tried turning off the a/c to see if temperature drops?