Brake ducts
Cars that have brake cooling ducts are specifically designed (as are the OEM parts) to perform well with the ducts. Even then I don't think high performance cars really do it anymore. Instead they force air around the wheel well itself to reduce drag and rely on higher quality components to handle the heat of high performance driving.
There have been people that have done this exact thing and have noticed that their rotors don't like it at all, cracking from the temperature differences. You're much better off getting rotors that handle and dissipate the heat more effectively than trying to rapidly cool off your stock rotors.
Start by flushing your fluid regularly. This will take care of any moisture in the system and you can upgrade to a better fluid as well. That will be more than enough for a street driven car that occasionally sees auto cross.
If you start doing some actual track days and you notice it's not longer enough, consider doing the CTS-V upgrade. The larger in diameter and thicker rotors will handle more heat from the extra mass. That will be enough for anything ouside of a full race car.
No matter what, just leave your rears alone. Quality OEM pads and rotors and you're golden. They don't do much at all and increasing their performance leads to horrible braking balance with a tendency for the rears to lock up before the front.






