Is it possible?
The thing that made the most difference for me was getting some little skinny SUV (road) tires (235/70/16 or something). And try not to use the brakes - if you drive so that you don't have to hit the brakes very much you're not wasting much energy as heat so you're converting most of the energy to forward motion not brake dust. And by not using the brakes I don't mean hit stuff, I mean accelerate slowly and leave a lot of room between you and the car in front, so that when they slow down or there is a red light you just come off the gas and coast until you need to hit the brakes. Modern engines have a mode called DFCO (deceleration fuel cut off) so that if you are above a certain RPM and come off the throttle you will use zero fuel (engine will be driven by the wheels). Use it, it works pretty well.
I don't think there's much you can do engine-wise to improve the mileage in a significant way. The OEMs pretty much set their vehicles up for pretty close to maximum mileage since they have to pay penalties on fleetwide mileage numbers.
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