Best cam for the job
If those heads your running are 5.7 (MILLED) forget about it. P/V clearance will be an issue. I had to exchange mine for 5.3 (UNMILLED) this cam however, should make some really nice power. From what I read in your post, you sound to me like retaining the driveability is more important that making MAX power, with that in mind, I would shoot for a cam between 220 and 224 duration, between 525 and 560 lift, and on a 112 lsa or higher. That should give you good power, excellent street manners, and a good sound.
Just as an FYI, if you search, you will find several people making 400+ with the 224/224 .563 cam on STOCK heads.
When I think about camshaft selection, there is a process of thinking my mind goes through. First, how many RPM's do you want to spin the engine up to? If you don't want to spin 6500-6800+ RPM, I see no reason going above 224 or 226 degrees of duration. Build your peak power where you plan on running the engine, don't get a cam that peaks above 7000 RPM if you know you're going to set your rev limiter at 6600.
Second, is it a 15,000 mile a year street car, or a 100 pass a year dragstrip car that gets trailered around? This is going to make a big difference in how much lift I plan on running, as well as how much lope I want. Here I'm thinking about how important idle quality is, as well as low RPM driveability, as well as valvetrain component life. Based on what these expectations are, I'm going to choose a LSA, or Overlap, and a valve lift that fits my application.
Finally if you want to get really scientific about it, there are a couple other things you should consider. You should match your cam to your cylinder head flow. To have optimized flow in your engine, there is a ratio of exhaust port flow to intake port flow that is considered ideal, generally 75%-85%. For arguments sake, let's just average it at 80%. When you have achieved this "ideal" ratio, you don't need to compensate with split durations to balance port flow. However, if you get outside this ideal flow ratio, then you should see duration growing on whichever side of the head that flows less than the ideal.
The math works out like this.. Say at a single given lift a head flows 300 on the intake and 240 on the exhaust. We'll make this our "ideal" head, just for an example.
240E/300I = 80% Pretty ideal, single pattern cam. 224/224
220E/310I = 71% Exhaust side weak, traditional split cam. 224/228
250E/285I = 88% Intake side weak, reverse split cam. 228/224
Again, these are just some random examples to show you how the theory works... I'm no cam expert, nor do I claim to be. Sorry for such a long post, but I hope it helps.
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It really does idle nice. 'Course a fully dyno tune makes that happen.

Also .. Thru MAC headers an ORY !Cats thru an electric cutout... It sounds sweet. Just enough lope to keep em guessin'

The 224 is a fun sweet spot.
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mine just has .563 lift though cause I was a pansey