cleaning aluminum block

As far as paint on aluminum, it just does not work (long term). It will stick in some places and come off in others. If you REALLY want the block to be some color, get a hold of a really good powder coat shop and have them powder coat it. It won't hurt the block as the temp they use is about 500degrees F. People powder coat aircraft engines, brake calipers, and trannys all the time. With that said, I would not powder coat it as I "think" it will run cooler being bare aluminum than coated. It also is easier to see cracks/leaks/etc on a clean block (I think).
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The strong Acid based aluminum wash will clean some parts. Like Eagle 1 - A wheel cleaner.
Once hte part is clean you can clear coat it, paint it with aluminum cast blast spray paint, or a basic aluminum color, or you can powder coat it.
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