Overheating After Turning the Car Off
You could be burning coolant, which will be white smoke out the back
You could be burning extra oil which will be oil smoke out the back
You could get coolant /oil mixed with each other.
Or it could just pressurize your dang system and cause you greif like it is now

I had this exact problem on a buick once, turned out to be a crack in the cylinder wall.
on cold start, pop off the rad. cap and start the car. if dex cool splashes out, then that's a bad sign, if nothing splashes out, it a good sign... hope this helps...
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Check for coolant in your oil and oil in your coolant. The first would show up as tan goo on the oil filler cap. The latter would show up as floating oil in your radiator.
A pressure test on the cooling system is not a bad idea. You don't need to do a flush to do the pressure test.
Go to http://www.blackstone-labs.com/ and order a test kit for a used oil analysis. That will check for coolant in your oil and provide other clues as to whether you have issues that may need to be addressed. You can either take your oil sample while you drain your oil or you can order a vacuum pump kit that removes it through the dipstick tube (for $25). However, I was unable to get the sample tube to fit all the way down the filler tube on my car and had to take it while draining the oil. It worked on the other three cars in our driveway.
There will be other replys from other posters that have more experience with your specific issue than have I. However, these things I mentioned are a good start. I'd get the oil test done ASAP, as that will definitely confirm whether there is coolant in your oil.
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eliminate any air from the heads. What is happening here is
the heads have a "pipeline" full of heat that is taken out by
coolant flow and when the coolant stops, the heat in the
"pipeline" can locally boil the water (against whatever the
coolant jacket pressure is, pressure is what suppresses boil).
Once it's steam rather than water there is much less heat
transfer and the aluminum around the ECT sensor can zing
right up. If you have air in the system it will tend to hang
out up in the heads making things worse this way.
Once you know there's good pressure integrity, get the
fans set to run -below- boiling temps (stock 'stat, try like
200/198 FAN2 and 196/194 FAN1 on/off).






