water pump???
It most certainly boiled. While pure water has better heat transfer properties than coolant, boiling point is still 211* (or is it 212*?). So coolant basically serves to expand the spectrum on both ends of the scale. That's not really your problem though. Air in the system will prevent water from flowing so I would look at that first. I myself am having cooling problems but I think mine is in the radiator because I am using the radiator that came with the car I bought and it had a blown head gasket so I'm thinking the radiator is filled with deposits.
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